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Kapton® HPP-ST Polyimide Coil

Available Configurations

Properties common to all products in this list

Grade: DuPont™ Kapton® HPP-ST Composition: PI Form: Coil Material: Polyimide (PI) CAS Number: 60842-76-4 Commodity: Polymers Thickness: 0.125mm Coil Width: 317.6mm Color: Amber
Length Other Grades
0.5m to 200m HN, FPC, MT, CRC, B, 200RS100

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Kapton® HPP-ST is DuPont's dual-surface-treated, high-performance polyimide film — the grade of choice when low residual shrinkage and superior adhesion to copper and bonding systems are the primary substrate selection criteria. It shares the full property profile of general-purpose Kapton® HN across the −269 °C to +400 °C thermal range, but its modified surface treatment delivers consistent adhesion of 10 pli (1.8 N/mm) to acrylic adhesive and copper foil across all four gauges, and its residual shrinkage of just 0.03 % after 30 minutes at 150 °C is significantly lower than standard HN — making it the preferred dielectric for multilayer flex circuits, rigid-flex PCB cores, and precision patterned substrates where dimensional shift during thermal processing causes registration error or yield loss. Available as 0.125 mm and certified to ASTM D-5213, Kapton® HPP-ST delivers a dielectric strength of up to 303 kV/mm at 25 µm, a volume resistivity of 1.5 × 10¹⁷ Ω·cm, a dielectric constant of 3.4 at 1 kHz, and a UL 94 V-0 flame rating. Its applications span electronic parts, PCB stencils, screen printing substrates, and insulation tubing — and wherever the dimensional precision of HN is insufficient for the tolerance requirements of the process.
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Key Features

Kapton® HPP-ST is DuPont's precision-stability polyimide film, formulated for demanding optical, lithographic, and high-accuracy electronic applications where dimensional repeatability is the overriding performance criterion:


Superior Dimensional Stability Under Thermal Cycling

Kapton® HPP-ST exhibits a lower residual shrinkage than standard Kapton® HN — just 0.03 % after 30 minutes at 150 °C across all gauges — minimising the pattern distortion and registration error that arise when films expand or contract during lamination, photolithography, or operational temperature swings. This characteristic makes it the preferred substrate for precision photomasks, rigid-flex PCB core layers, and any application where micron-level dimensional repeatability is non-negotiable.


Modified Surface for Superior Adhesion

The dual-surface treatment of HPP-ST promotes stronger, more consistent adhesion to copper foils, adhesive systems, and laminate materials compared with standard Kapton® HN. This translates to higher peel strengths, lower delamination risk during thermal excursions and chemical processing, and improved manufacturing yield in demanding multilayer flex circuit and substrate fabrication processes.


Exceptional Thermal Range (−269 °C to +400 °C)

HPP-ST retains the full thermal performance of the Kapton® family, maintaining dielectric strength, mechanical integrity, and dimensional stability from deep cryogenic environments to prolonged high-temperature service. This range covers the complete manufacturing process chain — from cryogenic testing of satellite sensor arrays to the high-temperature cure cycles of aerospace composite laminates.


High Dielectric Integrity (up to 303 kV/mm)

With a dielectric strength of up to 303 kV/mm at 25 µm, a volume resistivity of 1.5 × 10¹⁷ Ω·cm, and a stable dielectric constant of 3.4 at 1 kHz, Kapton® HPP-ST provides reliable high-voltage insulation in precision instrumentation, satellite electronics, and cryo-vacuum wiring systems. Its uniform refractive index of 1.70 additionally supports its use as a window or mask material in optical and photolithographic systems.


Radiation and Flame Resistance (UL 94 V-0)

Kapton® HPP-ST carries a UL 94 V-0 flame rating and has demonstrated good radiation resistance, making it suitable for the space and nuclear instrumentation environments where ionising radiation would degrade alternative polymer substrates. Its structural and dielectric integrity is maintained after exposure to the radiation doses encountered in satellite operation, particle physics diagnostics, and high-energy beam instrumentation.


Optical Uniformity for Lithographic & Diagnostic Applications

The high optical uniformity, consistent refractive index of 1.70, and low surface roughness of Kapton® HPP-ST make it suitable as a beam window, photomask substrate, or X-ray transmission window in analytical and diagnostic instruments. Its dimensional stability under repeated thermal and vacuum cycling ensures that optical and geometric calibration is maintained over the service life of the instrument.

Industrial Applications

Kapton® HPP-ST is specified wherever the dimensional precision and processing consistency of the polyimide substrate are as critical as its thermal or electrical performance:

Rigid-Flex PCBs & High-Accuracy Multilayer Circuits
The core dielectric layer in rigid-flex PCBs for satellite electronics, military avionics, and high-reliability computing modules, where the HPP-ST's lower residual shrinkage and superior adhesion enable precise via-to-pad registration across large, thermally stressed multilayer assemblies. Reduces scrap rates and rework in high-value flex circuit fabrication.
Space & Satellite Sensor Encapsulation
Used as a precision encapsulant and structural insulator in satellite attitude sensors, star trackers, and optical bench assemblies, where thermal stability across the full space environment temperature range (−200 °C to +150 °C operational) must be maintained without dimensional shift that would compromise alignment or signal path geometry.
Cryogenic Electronics & Superconducting Systems
Specified as the insulating substrate in cryogenic wiring looms, superconducting magnet interconnects, and dilution refrigerator wiring harnesses, where its lower residual shrinkage reduces the thermomechanical stress generated during cool-down cycles and its stable dielectric performance ensures insulation integrity at liquid helium temperatures.
Photolithographic Masking & Precision Patterning
Applied as a photomask base and precision patterning substrate in semiconductor and MEMS fabrication, where its dimensional stability across humidity and temperature changes allows accurate alignment across multiple lithographic exposures. Its optical uniformity supports both UV and deep-UV mask applications.
Particle Physics & Beam Diagnostics
Used as a window and detector substrate in particle beam diagnostics, scintillator assemblies, and heavy-ion imaging systems at major physics research facilities, where its radiation tolerance, dimensional stability under irradiation, and low atomic number (minimal beam perturbation) make it the material of choice for beam-intercepting instrumentation.
Advanced Instrumentation & Metrology
The dimensional stability and optical uniformity of Kapton® HPP-ST are exploited in precision analytical instruments including X-ray fluorescence windows, infrared transmission cells, laser beam-shaping apertures, and interferometric sensor substrates, where substrate distortion would directly degrade measurement accuracy.
Medical Imaging & Diagnostic Device Electronics
Specified in the flex circuit assemblies of MRI-compatible electronics, diagnostic wearables, and high-density sensor arrays, where the combination of dimensional stability, polyimide chemistry, and sterilisation resistance ensures long-term reliability in body-worn and hospital environments subjected to repeated thermal and chemical cycling.

Frequently Asked Questions

Answers to the questions we are asked most often about Kapton® FPC Polyimide Film, covering what distinguishes it from standard HN, its flex circuit applications, processing, and how to choose the right grade:

What is Kapton® FPC and how does it differ from standard Kapton® HN?

Kapton® FPC is DuPont's dedicated flexible circuit polyimide film. It shares the same base polymer chemistry as Kapton® HN — and the same −269 °C to +400 °C thermal range, high dielectric strength, radiation resistance, and UL 94 V-0 flammability rating — but has two key differences: a dual-sided adhesion treatment that promotes reliable bonding to both rolled-annealed and electrodeposited copper foils, and tighter dimensional stability under thermal processing. It is IPC-4202/1 compliant, making it the correct dielectric substrate choice wherever a qualification standard for flexible circuits is specified. Standard HN has an untreated surface and greater dimensional variability under heat — adequate for general insulation, masking, and research, but not optimised for fine-line copper lamination.

What does the IPC-4202/1 certification mean in practice?

IPC-4202/1 is the industry standard for flexible base dielectric materials used in flexible printed circuit construction. Kapton® FPC's compliance with this standard confirms that it meets the dimensional stability, adhesion promotion, electrical, and thermal requirements that flex circuit manufacturers specify as a baseline for copper-clad laminate qualification. For aerospace, automotive, and medical flex circuit programmes where the substrate must be traceable to a published standard, FPC's IPC certification is often a hard procurement requirement.

What makes Kapton® FPC suited to fine-line and high-density flex circuits?

Fine-line and HDI flex circuits fail in registration when the substrate shifts dimensionally during lamination, etching, or thermal cure cycles. Kapton® FPC's tighter control of residual shrinkage and superior lay-flat characteristics compared with HN reduce the pattern distortion that causes trace misalignment across multilayer stacks. Combined with its adhesion-treated surface — which promotes consistent peel strength to copper foil without delamination during thermal excursions — it is the substrate that allows fine-pitch, high-yield flex circuit fabrication.

What thermal range does Kapton® FPC cover?

Like all standard Kapton® grades, FPC has a continuous service range from −269 °C to +400 °C. This means it survives solder reflow, conformal coating cure, and all standard PCB processing steps without dimensional change or property degradation, and remains functional in the cryogenic environments of aerospace and scientific instrumentation at the other end of the scale.

What are the main application areas for Kapton® FPC?

Kapton® FPC is the standard substrate for flexible printed circuits in smartphones, tablets, and laptops (connector cables, camera module flex, antenna feeds); automotive ADAS sensor arrays and EV powertrain control flex; aerospace avionics flex interconnects and satellite sensor assemblies; medical wearable biosensors, hearing aid circuits, and body-worn diagnostic platforms; industrial robot continuous-flex cable chains; and HDI rigid-flex PCBs in defence electronics and high-performance computing modules. Any application where a polyimide substrate must flex dynamically, hold fine-pitch registration through thermal processing, and bond reliably to copper specifies FPC by default.

Is Kapton® FPC suitable for dynamic flex applications?

Yes. Kapton® FPC maintains its mechanical integrity through sustained repeated flexing without crack initiation or delamination from the copper layer — a critical requirement for foldable displays, articulating robotic harnesses, drawer connector cables, and any assembly subject to millions of flex cycles in service. Its elongation and tensile modulus are balanced to absorb repeated bending stress without fracturing or causing trace cracking at the substrate-copper interface.

How is Kapton® FPC processed for flex circuit manufacturing?

Kapton® FPC is compatible with standard flex circuit processing chemistry including the etchants, plating solutions, and adhesive systems used in copper-clad laminate manufacture. It can be laser-drilled and ablated for via formation, die-cut or laser-profiled for outline shaping, and processed through roll-to-roll lamination lines. Its surface treatment is formulated to bond to acrylic and epoxy adhesive systems as well as to both rolled-annealed and electrodeposited copper foils.

Is Kapton® FPC suitable for medical applications?

Kapton® FPC is sterilisation-resistant and has been used in body-worn medical sensor platforms, wearable diagnostic devices, and hearing device flex circuits. It is not suitable for permanent implantation in the human body or direct contact with internal body fluids or tissues. Applications requiring implant-grade biocompatibility should be evaluated under ISO 10993.

When should I choose FPC over HN or HPP-ST?

Choose FPC when the primary requirements are copper adhesion and IPC-4202/1 compliance for flex circuit manufacture. It is the standard substrate selection for any application involving copper lamination and fine-line patterning. Choose HN instead if the application is a general insulation, masking, or research use that does not involve copper lamination and does not need a flex circuit qualification standard. Choose HPP-ST over FPC when dimensional stability is the overriding criterion — HPP-ST has lower residual shrinkage than FPC and is the grade for the most demanding registration-sensitive applications such as satellite sensor encapsulation and multilayer rigid-flex assemblies.

Material Properties

Chemical Resistance
Element Value
Acids - concentrated Poor
Acids - dilute Fair
Alcohols Poor
Alkalis Poor
Aromatic hydrocarbons Good
Greases and Oils Good
Halogenated Hydrocarbons Good
Halogens Fair
Ketones Good
Mechanical Properties
Element Value
Coefficient of friction 0.42
Hardness - Rockwell E52-99
Elongation at break( % ) Aug-70
Tensile modulus( GPa ) 2.0 – 3.0
Izod impact strength( J m⁻¹ ) 80
Tensile strength( MPa ) 70-150
Electrical Properties
Element Value
Dielectric constant @1MHz 3.4
Dissipation factor @ 1kHz 0.0018
Dielectric strength( kV mm⁻¹ ) 154 – 303
Surface resistivity( Ohm/sq ) 10¹⁶
Volume resistivity( Ohmcm ) 10¹⁸
Physical Properties
Element Value
Flammability V0
Radiation resistance Good
Refractive index 1.66
Resistance to Ultra-violet Poor
Limiting oxygen index( % ) 53
Water absorption - over 24 hours( % ) 0.2-2.9
Density( gcm⁻³ ) 1.42
Thermal Properties
Element Value
Heat-deflection temperature - 1.8MPa( C ) 360
Lower working temperature( C ) -270
Upper working temperature( C ) 250-320
Specific heat( J K⁻¹ kg⁻¹ ) 1090
Thermal conductivity( W m⁻¹ K⁻¹ ) 0.1-0.35@23°C
Coefficient of thermal expansion( x10⁻⁶ K⁻¹ ) 30-60
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Available Configurations

Properties common to all products in this list

Grade: DuPont™ Kapton® HPP-ST Composition: PI Form: Coil Material: Polyimide (PI) CAS Number: 60842-76-4 Commodity: Polymers Thickness: 0.125mm Coil Width: 317.6mm Color: Amber

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Tolerances

Coil
Thickness ±20%
Coil Width <100mm ±1mm
Coil Width >=100mm +2% / -1%
Length +10% / -0%