Bismuth Top Hat Single Crystal

Bismuth Top Hat Single Crystal is a highly specialized form of elemental bismuth engineered with a precise single-crystal structure to maximize anisotropic electrical, thermal, and magnetic properties. Its top-hat geometry facilitates integration into precision instrumentation, quantum devices, and specialized cryogenic systems where exact orientation and stability are essential. Industries such as condensed matter physics, magneto-optics, and thermoelectrics employ these crystals for applications requiring reproducible surface states, minimal defects, and predictable carrier dynamics. Specific uses include serving as calibration standards for magneto-optical Kerr effect measurements, substrates for epitaxial thin-film growth, and model systems for studying topological insulator behavior. In research, the controlled growth of bismuth top hat crystals enables detailed investigations into electron–phonon interactions, quantum size effects, and strain-dependent transport phenomena. Combining crystalline perfection, geometric precision, and unique physical constants, they remain indispensable in advancing both fundamental scientific inquiry and next-generation device engineering.

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Tolerance

Properties

Reference & Citations

each

Tolerances

Single Crystal

Orientation		See Item
Thickness		+2% / -1%
Length		+2% / -1%

Top Hat

Inside Diameter		+2% / -1%
Outside Diameter		+2% / -1%
Bottom Section Thickness		+2% / -1%
Top Section Thickness		+2% / -1%

Material Properties for Metals

Atomic Properties

Element	Value
Atomic number	83
Crystal structure	Rhombohedral
Electronic structure	Xe 4f¹⁴ 5d¹⁰ 6s² 6p³
Valences shown	3, 5
Atomic weight( amu )	208.9804
Thermal neutron absorption cross-section( Barns )	0.034
Photo-electric work function( eV )	4.4
Atomic radius - Goldschmidt( nm )	0.182
Ionisation potential( No./eV )	5/ 56.0
Ionisation potential( No./eV )	1/ 7.29
Ionisation potential( No./eV )	3/ 25.6
Ionisation potential( No./eV )	4/ 45.3
Ionisation potential( No./eV )	6/ 88.3
Ionisation potential( No./eV )	2/ 16.7

Mechanical Properties

Element	Value
Material condition	Polycrystalline
Poisson's ratio	0.33
Bulk modulus( GPa )	31.3
Tensile modulus( GPa )	34
Hardness - Vickers( kgf mm⁻² )	16-19

Electrical Properties

Element	Value
Electrical resistivity( µOhmcm )	117@20@20°C
Temperature coefficient( K⁻¹ )	0.0046@0-100°C
Thermal emf against Pt (cold 0C - hot 100C)( mV )	-7.34

Physical Properties

Element	Value
Boiling point( C )	1560
Density( gcm⁻³ )	9.8@20°C

Thermal Properties

Element	Value
Melting point( C )	271.3
Latent heat of evaporation( J g⁻¹ )	857
Latent heat of fusion( J g⁻¹ )	52
Specific heat( J K⁻¹ kg⁻¹ )	124@25°C
Thermal conductivity( W m⁻¹ K⁻¹ )	7.9@0-100°C
Coefficient of thermal expansion( x10⁻⁶ K⁻¹ )	13.4@0-100°C