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PMMA Film/Sheet

Available Configurations

Properties common to all products in this list

Commodity: Polymers Material: Polymethyl methacrylate (PMMA) Form: Foil/Film/Sheet Composition: PMMA, Acrylic CAS Number: 9011-14-7
Thickness Size
0.175 mm (film) to 25 mm 10 x 10 mm to 1000 x 1000 mm

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PMMA Film (polymethyl methacrylate) is a transparent thermoplastic film and sheet material with a refractive index of 1.49, density of 1.19 g/cm³, tensile strength of 80 MPa, Rockwell hardness of M92–100, and good UV resistance, available from thin film through to structural sheet thickness. Its high optical clarity, the highest light transmission of any common polymer, combined with UV stability and good weatherability makes it the standard material for optical filters, light guide elements, solar panel encapsulants, and glazing applications where transparency and outdoor durability are both required. In electronics and microfabrication, PMMA is the most widely studied and used electron beam lithography resist: it achieves sub-10 nm feature resolution in negative tone and is capable of patterning at single-nanometre length scales under aberration-corrected EBL conditions, making it the reference resist for nanofabrication research. It is also used in UV photolithography across both long and short UV wavelengths, providing versatile lithographic performance in positive and negative tone depending on exposure conditions. Microfluidic device fabrication exploits PMMA's optical transparency, machinability, and compatibility with hot embossing and solvent bonding for the production of lab-on-chip analytical systems. In biomedical packaging, it provides a chemically stable, visually inspectable enclosure material. Its moderate chemical resistance to alkalis and greases makes it suitable for general laboratory and industrial protective glazing applications, though exposure to aromatic hydrocarbons and ketones should be avoided.
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Key Features

PMMA Film (polymethyl methacrylate) is a transparent thermoplastic film and sheet with a refractive index of 1.49, density of 1.19 g/cm³, tensile strength of 80 MPa, and Rockwell hardness of M92–100, available from 0.175 mm film through to 25 mm structural sheet:

Highest Light Transmission of Any Common Polymer

PMMA provides the highest optical clarity and light transmission of any widely available polymer, combined with UV stability and good weatherability, establishing it as the standard material for optical filters, light guide elements, solar panel encapsulants, and outdoor glazing.

Reference Electron Beam Lithography Resist

PMMA is the most widely studied and used EBL resist, achieving sub-10 nm feature resolution and capable of patterning at single-nanometre length scales under aberration-corrected conditions. It is the reference positive-tone resist for nanofabrication research and sub-100 nm device fabrication.

UV Photolithography Compatibility

Used in UV photolithography across both long and short UV wavelengths, providing versatile positive and negative tone lithographic performance depending on exposure conditions.

Tensile Strength 80 MPa, Rockwell Hardness M92–100

Good mechanical stiffness and surface hardness provide scratch resistance and dimensional stability in optical components, protective glazing, and structural sheet applications.

UV Stability and Weatherability

Resistance to UV-induced yellowing and degradation supports long-term outdoor performance in solar panel encapsulants, architectural glazing, and signage applications where other polymers would discolor or embrittle.

Hot Embossing and Solvent Bonding Compatibility

Compatibility with hot embossing and solvent bonding processes makes PMMA the preferred substrate for microfluidic lab-on-chip device fabrication, where channels and features are imprinted or bonded to produce sealed analytical devices.

Industrial Applications

PMMA Film is used across optics, lithography, microfluidics, and protective glazing wherever optical clarity, UV stability, and compatibility with precision patterning processes determine material selection:

✦ Optical Filters, Light Guides and Solar Panel Encapsulants
Used in optical filters, light guide panels, and solar panel encapsulants where the highest light transmission of any common polymer combined with UV stability and weatherability produces durable, high-performance optical components for indoor and outdoor service.
✦ Electron Beam Lithography Resist
The reference positive-tone EBL resist in nanofabrication research and semiconductor device fabrication, where sub-10 nm feature resolution and compatibility with standard development processes make it the first-choice resist for patterning at the nanometre scale.
✦ UV Photolithography
Applied as a photolithographic resist in UV exposure processes, providing positive or negative tone patterning depending on exposure conditions across a range of UV wavelengths.
✦ Microfluidic Lab-on-Chip Devices
Used as the substrate for microfluidic device fabrication by hot embossing and solvent bonding, where optical transparency for on-chip optical detection, machinability, and bonding compatibility combine to produce functional analytical devices.
✦ Protective Glazing and Architectural Applications
Applied as impact-resistant, UV-stable glazing in architectural, signage, and industrial protective panel applications where optical clarity must be maintained over extended outdoor service life.
✦ Biomedical Packaging
Used as a chemically stable, visually inspectable enclosure material in biomedical packaging where sterility assurance through visual inspection of contents is required.

Material Properties

Physical Properties
Element Value
Abbe number 57.2
Flammability HB
Radiation resistance Fair
Refractive index 1.49
Resistance to Ultra-violet Good
Limiting oxygen index( % ) 17-20
Water absorption - over 24 hours( % ) 0.2
Density( gcm⁻³ ) 1.19
Chemical Resistance
Element Value
Acids - concentrated Good-Poor
Acids - dilute Good-Poor
Alcohols Good-Poor
Alkalis Good
Aromatic hydrocarbons Poor
Greases and Oils Good
Halogenated Hydrocarbons Poor
Halogens Poor
Ketones Poor
Electrical Properties
Element Value
Dielectric constant @1MHz 2.6
Dissipation factor @ 1MHz 0.014
Dielectric strength( kV mm⁻¹ ) 15
Surface resistivity( Ohm/sq ) 10¹⁴
Volume resistivity( Ohmcm ) 2-14 x 10¹⁵
Mechanical Properties
Element Value
Hardness - Rockwell M92-100
Poisson's ratio 0.35-0.4
Elongation at break( % ) 2.5-4
Tensile modulus( GPa ) 2.4-3.3
Izod impact strength( J m⁻¹ ) 16-32
Tensile strength( MPa ) 80
Thermal Properties
Element Value
Heat-deflection temperature - 0.45MPa( C ) 105
Heat-deflection temperature - 1.8MPa( C ) 95
Lower working temperature( C ) -40
Upper working temperature( C ) 50-90
Specific heat( J K⁻¹ kg⁻¹ ) 1400-1500
Thermal conductivity( W m⁻¹ K⁻¹ ) 0.17-0.19@23°C
Coefficient of thermal expansion( x10⁻⁶ K⁻¹ ) 70-77
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Available Configurations

Properties common to all products in this list

Commodity: Polymers Material: Polymethyl methacrylate (PMMA) Form: Foil Composition: PMMA, Acrylic CAS Number: 9011-14-7

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Tolerances

Foil
Thickness ±20%
Linear dimension <100mm ±1mm
Linear dimension >=100mm +2 / -1%