Yttrium

Yttrium — Material Page
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Yttrium (Y, atomic number 39) is a silvery-white HCP transition metal in Group 3 — lightweight (4.47 g/cm³), melting point 1,526 °C, 4d¹5s², exclusively trivalent — which behaves geochemically and chemically as a heavy rare-earth element (HREE) due to its ionic radius (Y³⁺: 0.900 Å in 6-coordination), closely matching Ho³⁺. ⁸⁹Y is the only natural isotope (monoisotopic, 100%, stable, I = 1/2, NMR-active). Despite a crustal abundance of ~33 ppm (comparable to cobalt), Y is classified as critical due to its concentrated extraction in China from REE ores.

Y₂O₃ (yttria) is one of the most industrially important rare-earth oxides: YSZ (yttria-stabilised zirconia, 3–8 mol% Y₂O₃) is the standard electrolyte for high-temperature SOFCs and the dominant thermal barrier coating (TBC) material in aircraft and gas turbine engine hot-section components — the ~250 µm plasma-sprayed YSZ TBC on Ni-superalloy blades enables turbine inlet temperatures of 1,400–1,600 °C, far above the Ni-alloy melting point, directly enabling the fuel efficiency and power-to-weight ratio of modern jet engines. Y₂O₃-stabilised ZrO₂ is also the electrolyte in solid oxide fuel cells (Siemens, Bloom Energy) operating at 800–1,000 °C and the standard matrix for Nd:YAG, Er:YAG, Ho:YAG, and Yb:YAG laser crystals.

Y₃Al₅O₁₂:Ce³⁺ (YAG:Ce) is the dominant white LED phosphor globally — Ce³⁺ ⁵d→⁴f broadband yellow emission (500–700 nm) converts blue GaN LED emission (450 nm) to white light through partial down-conversion, with internal quantum efficiency >95% — and is used in virtually every white LED for general illumination, automotive headlights, projectors, and backlighting. ⁹⁰Y (t½ = 64.1 hr, β⁻ 2.28 MeV max, produced from ⁹⁰Sr/⁹⁰Y generator or cyclotron) is the active radioisotope in Y-90 microsphere liver radioembolisation (SIR-Spheres, TheraSphere) for hepatocellular carcinoma and liver metastases, and in ⁹⁰Y-DOTATOC/DOTATATE PRRT for neuroendocrine tumours. YBCO (YBa₂Cu₃O₇) is the most commercially important high-temperature superconductor (T_c = 92 K), used in MRI magnets, superconducting power cables, and HTS fault current limiters.

General Properties

PropertyValueNotes
Atomic Number39 4d¹5s²; +3 the only stable oxidation state. Y³⁺ ionic radius (0.900 Å, 6-coordinate) matches Ho³⁺ — Y substitutes for Ho and other HREEs in garnets, phosphors, and oxide ceramics without charge compensation. ⁸⁹Y (I = 1/2) is NMR-active: ⁸⁹Y NMR characterises Y³⁺ environments in YSZ electrolytes, YAG laser crystals, and YBa₂Cu₃O₇ superconductor grain boundaries.
Atomic Mass88.906 uMonoisotopic: ⁸⁹Y (100%, stable). Single ICP-MS signal at m/z 89. ⁹⁰Y (t½ = 64.1 hr, β⁻ 2.28 MeV max; produced from ⁹⁰Sr/⁹⁰Y generator equilibrium or by ⁸⁹Y(n,γ) activation) is the therapeutic radioisotope in liver radioembolisation microspheres and PRRT.
Density (20 °C)4.47 g/cm³Low density for a transition metal; comparable to Ti (4.51 g/cm³). Y is one of the lightest metals with a melting point above 1,500 °C, relevant to lightweight high-temperature alloy and ceramic applications.
Melting Point1,526 °C (1,799 K)High melting point. Y is produced by Ca-reduction of YF₃; processed under Ar or vacuum. More stable in air than the lanthanides.
Boiling Point3,345 °CHigh boiling point. Y evaporation sources are used in MBE and PLD deposition of YBCO thin films and Y-doped oxide dielectric layers.
Thermal Conductivity17 W/m·KModerate conductivity. YSZ TBC thermal conductivity (~2.3 W/m·K) is much lower than the Y metal — the insulating ceramic layer, not the metal, provides the thermal barrier function.
Electrical Resistivity59 nΩ·m (20 °C)Moderate resistivity. Not relevant to most Y applications. Y becomes superconducting at ~1.3 K under ambient pressure.
Crystal StructureHCP, a = 3.648 Å, c = 5.732 ÅHCP at RT; transforms to BCC above ~1,478 °C. Y lattice parameters lie between those of Ho and Er, consistent with its behaviour as a HREE surrogate in crystal chemistry.

Mechanical Properties

PropertyValueNotes
Tensile Strength150 MPaLow tensile strength for a refractory metal. Y is not used structurally; its mechanical properties are relevant to Y foil and rod fabrication for alloying additions and sputtering targets.
Young's Modulus63 GPaModerate modulus. YAG single crystal (280 GPa) and YSZ ceramic (200–210 GPa) are much stiffer than the metal; thermal stress calculations use ceramic/crystal elastic constants.
Hardness~38–44 HB (annealed)Soft for a refractory metal; can be machined under standard conditions. Y is more air-stable than lanthanides and can be briefly handled in ambient air.
Elongation at Break~30%Good ductility; Y rod and foil (99.9%+) are used as sputtering targets for YBCO and YSZ thin-film deposition and as micro-addition master alloy precursors.
Poisson's Ratio0.24Typical for an HCP metal.

Chemical Properties

PropertyValue / BehaviorNotes
Oxidation States+3 only (Y³⁺: YCl₃, Y₂O₃, Y(NO₃)₃·6H₂O)Y³⁺ follows identical coordination chemistry to the HREEs; EDTA, DOTA, and DTPA chelates of Y³⁺ have stability constants matching Ho³⁺ and Er³⁺ — relevant to ⁹⁰Y-DOTA-TATE PRRT radiopharmaceutical design and REE separation process development.
Corrosion ResistanceGood; forms adherent Y₂O₃ passive layer; more stable in air and water than the lanthanidesY is significantly more corrosion-resistant than La, Ce, Nd, or Pr; rod and foil can be handled in air for extended periods. Y additions to Fe and Ni alloys improve oxidation resistance by increasing oxide scale adhesion and reducing oxide growth rate.
Surface OxideY₂O₃ (cubic C-type, transparent) forms in airY₂O₃ (mp ~2,425 °C) is used as a ZrO₂ stabiliser (YSZ), YAG/YIG/YVO₄ laser and phosphor host precursor, YBCO superconductor component, Y₂O₃ sintering aid in Si₃N₄/AlN ceramics, and ⁹⁰Y target material. Transparent Y₂O₃ ceramics are studied for high-power laser windows and scintillators.
IdentifierValue
SymbolY
Atomic Number39
CAS Number7440-65-5
UN NumberUN3089 (powder)
EINECS Number231-174-8
IsotopeTypeNotes
⁸⁹YStable100%; I = 1/2, NMR-active. Monoisotopic. ⁸⁹Y NMR (I = 1/2; narrow lines; chemical shift range ~1,500 ppm) characterises Y³⁺ coordination in YSZ electrolytes (cubic vs. tetragonal phase discrimination), YAG laser crystal precursor solutions, and YBCO superconductor grain boundary chemistry. The single ICP-MS signal at m/z 89 makes Y a reliable trace-element monitor in geological and metallurgical analysis; Y/Ho ratio is a highly sensitive indicator of seawater vs. hydrotherm-derived REE in marine geochemistry. σ(thermal) = 1.28 barn; ⁸⁹Y(n,γ)⁹⁰Y (t½ = 64.1 hr, β⁻ 2.28 MeV max + 1.76 MeV γ at 0.01% abundance) produces the therapeutic radioisotope ⁹⁰Y used in liver radioembolisation microspheres (SIR-Spheres, TheraSphere) and PRRT of neuroendocrine tumours.

Scientific & Research Applications

Use CaseForm Typically UsedDescription
YBCO High-Temperature Superconductor ResearchYBCO (YBa₂Cu₃O₇₋δ) thin films by PLD or sputtering; YBCO coated conductors (RABiTS/IBAD substrate tapes); 99.9%+ Y₂O₃ precursorYBCO (T_c = 92 K, liquid nitrogen cooled) is the most commercially developed HTS material. Research focuses on enhancing flux pinning (via BaZrO₃, BaHfO₃, Y₂O₃ nanorod inclusions), manufacturing kilometre-length coated conductor tape for power cables and MRI insert coils, and fault current limiters for grid protection.
YSZ Electrolyte & TBC Research8-YSZ (8 mol% Y₂O₃-ZrO₂) plasma-spray powder; 3-YSZ tetragonal electrolyte tape; 99.9%+ Y₂O₃ precursorYSZ TBC research addresses thermal cycling durability (>10,000 cycles at 1,200 °C surface temperature), CMAS (calcium-magnesium-aluminosilicate) resistance from sand/ash ingestion, and alternative compositions (rare-earth zirconates, pyrochlores) for >1,300 °C applications beyond YSZ stability limit.
⁹⁰Y Radiopharmaceutical Research⁹⁰YCl₃ (from ⁹⁰Sr/⁹⁰Y generator or irradiation); ⁹⁰Y-DOTA conjugates⁹⁰Y (pure β⁻ emitter, mean tissue range ~4 mm, max 11 mm) is conjugated to DOTATOC/DOTATATE (PRRT for somatostatin-positive neuroendocrine tumours) and to glass/resin microspheres for selective internal radiation therapy (SIRT) of liver tumours. Unlike ¹⁷⁷Lu, ⁹⁰Y emits no γ — bremsstrahlung SPECT or PET with ⁹⁰Y PET (0.003% pair production) is used for post-treatment dosimetry.
⁸⁹Y NMR SpectroscopyYCl₃ or Y(NO₃)₃ solution standards; Y-doped solid powders⁸⁹Y solution NMR characterises Y³⁺ coordination in REE separation solvent systems, DOTA/DTPA chelate complexes for radiopharmaceutical design, and Y-containing battery electrolytes. Solid-state ⁸⁹Y NMR (MAS) provides phase discrimination in YSZ (cubic vs. tetragonal) and structural information in YAG, YIG, and YVO₄ host lattices.

Industrial & Commercial Applications

SectorForm / Grade UsedDescription
YSZ Thermal Barrier Coatings8-YSZ plasma-spray powder (45–105 µm) and EB-PVD ingots (99.9%+ Y₂O₃ precursor); columnar 8-YSZ TBC by EB-PVDYSZ TBC (~250 µm) plasma-sprayed or EB-PVD deposited on Ni-superalloy blades and vanes in every commercial jet engine and gas turbine. The low thermal conductivity (~2.3 W/m·K) of 8-YSZ allows turbine inlet temperatures 100–200 °C above the Ni-alloy melting point, directly enabling the fuel efficiency of modern high-bypass turbofan engines. Global TBC market consumes thousands of tonnes of Y₂O₃ per year.
YAG:Ce White LED PhosphorsY₃Al₅O₁₂:Ce³⁺ (YAG:Ce) phosphor powder or ceramic plates (99.9%+ Y₂O₃ and Al₂O₃ precursors)YAG:Ce is the standard phosphor in blue-pumped white LEDs for general illumination, automotive headlights, and projectors. Ce³⁺ ⁵d→⁴f broadband yellow emission (530–570 nm peak) combines with residual blue to produce white light with CRI 70–90. Each high-power LED package contains ~10–100 mg of YAG:Ce; global LED phosphor demand drives significant Y₂O₃ consumption.
SOFC Electrolytes (8-YSZ)8-YSZ tape-cast electrolyte (99.9%+ Y₂O₃ precursor); 3-YSZ for high-strength anode-supported cellsYSZ electrolyte is used in commercial HT-SOFC stacks (Siemens, Bloom Energy, Kyocera) operating at 800–1,000 °C for stationary power generation. Each kW of SOFC capacity contains ~5–15 g Y₂O₃. YSZ electrolytes are being complemented by ScSZ (higher conductivity) and GDC (lower temperature) in next-generation SOFC designs.
Laser Crystal Hosts (YAG, YLF, YVO₄)Y₃Al₅O₁₂ (YAG), YLiF₄ (YLF), YVO₄ single crystals grown from Y₂O₃ + activator ion precursors (Czochralski or Bridgman)Y provides the host lattice for virtually all rare-earth-doped solid-state lasers: Nd:YAG (1,064 nm), Er:YAG (2,940 nm), Ho:YAG (2,090 nm), Yb:YAG (1,030 nm), Tm:YAG (2,013 nm), and Er:YLF, Nd:YVO₄. YAG's high thermal conductivity (10 W/m·K), cubic symmetry, and chemical stability make it the pre-eminent laser host material. Global laser crystal market for Y-containing hosts exceeds several hundred tonnes of Y₂O₃/year.
PurityApplicationsNotes
99% (2N)Ceramics, metallurgy, and electronic components.Cost-effective grade for industrial-scale processes.
99.9% (3N)Photonics, superconductors, and nuclear research.High-purity grade essential for sensitive and high-tech applications.
Synonym / Alternative NameContext
YChemical symbol; from Ytterby (Sweden), the same village that gave its name to Tb, Er, and Yb. Used in YSZ TBC specifications, YAG laser crystal datasheets, YBCO superconductor literature, and ICP-MS REE databases (m/z 89, Y/Ho ratio as marine geochemistry proxy).
Y metalCommercial form designation for ingot, rod, foil, or powder. Used in YBCO thin-film sputtering target specs, Y-addition master alloy procurement, and ⁹⁰Y radiopharmaceutical target material documentation.
Y elementScientific designation used in ⁸⁹Y NMR spectroscopy and crystal chemistry literature (Y³⁺ as HREE surrogate in garnet and oxide ceramics).
Yttrium metalFull commercial designation in REACH/RoHS documentation, ASTM REE metal standards, and jet engine TBC material qualification documents.
Yttrium elementUsed in academic databases, YBCO superconductor physics publications, YSZ electrolyte science texts, and ⁹⁰Y radiopharmaceutical nuclear medicine literature.
Yttrium rare earth metalTrade designation; Y is classified as critical on EU and US materials lists. Critical applications in YSZ TBCs (jet engines), YAG:Ce LED phosphors, YBCO superconductors, and ⁹⁰Y radiopharmaceuticals drive demand, with China dominating global REE separation and Y₂O₃ production.
Yttrium rare earth elementGeochemical designation; Y behaves as a HREE (co-precipitates with HREEs in garnet, monazite, and xenotime) and its Y/Ho ratio is one of the most sensitive geochemical tracers of marine vs. hydrothermal REE sources, since seawater preferentially enriches Y relative to Ho through carbonate complexation.
Element 39Periodic table designation used in XRF/ICP-MS software, nuclear data libraries (⁸⁹Y neutron activation, ⁹⁰Y β⁻ decay data for SIRT dosimetry), and reactor physics codes tracking ⁹⁰Y as daughter of ⁹⁰Sr fission product.