Gold

Gold — Material Page
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Gold (Au, atomic number 79) is a Group 11 FCC noble metal with a melting point of 1,064 °C, density of 19.32 g/cm³, and the most chemically inert character of any metal — it does not react with oxygen, water, or most acids, dissolving only in aqua regia (HNO₃/HCl, 1:3) and in cyanide solutions in the presence of oxygen. Gold's chemical stability arises from relativistic contraction of the 6s orbital, which lowers its energy and increases the ionization potential — the same relativistic effect accounts for gold's characteristic yellow color (relativistic narrowing of the 5d→6s band gap allows absorption of blue light) and its anomalously high electron affinity for a metal. Gold is the most malleable and ductile of all metals: 1 gram can be beaten to a 1 m² leaf (~0.1 µm thick) or drawn to ~3 km of wire. It occurs as native metal in quartz veins and alluvial deposits, and is the only metal historically obtained without smelting.

Electronics is the largest technical application of gold (~300 tonnes/year), exploiting its unique combination of chemical inertness, electrical conductivity, and reliability: Au bond wires connect semiconductor die to package leads, Au electroplating protects connector contacts, and Au-based solders (Au-Sn, Au-Ge, Au-Si eutectic alloys) provide hermetic sealing in high-reliability packages for aerospace, defense, and medical devices. Gold's surface plasmon resonance (SPR) — collective oscillation of conduction electrons at ~520 nm in Au nanoparticles, tunable from 500–900 nm with particle size and shape — is the basis of a vast range of biosensing, diagnostic, and therapeutic applications. Colloidal Au nanoparticles (AuNPs, 5–100 nm) functionalized with antibodies, oligonucleotides, or peptides are the active element in lateral flow immunoassays (home pregnancy tests, COVID-19 rapid tests, ~1 billion produced/year) and in surface-enhanced Raman spectroscopy (SERS) substrates for single-molecule detection.

Nanoparticulate gold catalysis — discovered by Masatake Haruta in 1987 — revealed that Au, long considered catalytically inert, becomes highly active for CO oxidation at room temperature when deposited as ~2–5 nm particles on reducible oxide supports (TiO₂, Fe₂O₃, CeO₂), a finding that overturned a fundamental assumption of catalytic chemistry. Au/TiO₂ catalysts operate at temperatures as low as –70 °C for CO oxidation, relevant to CO sensors, air purification, and preferential oxidation of CO in H₂ streams for fuel cells. The combination of biocompatibility, ease of surface functionalization via Au-thiol self-assembled monolayers, and tunable SPR makes gold the pre-eminent substrate for scanning tunneling microscopy (STM), surface-enhanced spectroscopies, and biosensor development. ¹⁹⁸Au (t½ = 2.7 days, β⁻/γ) has been used clinically for radiation synovectomy and solid tumor treatment, and gold-198 nanoparticles are in clinical development for prostate cancer brachytherapy.

General Properties

PropertyValueNotes
Atomic Number79Group 11, Period 6; 4f¹⁴5d¹⁰6s¹; oxidation states +1 (Au⁺, aurous, stable in AuCN and Au₂S) and +3 (Au³⁺, auric, stable in AuCl₄⁻ and HAuCl₄). Relativistic contraction of the 6s orbital is unusually large at Z=79, raising Au's ionization energy and electron affinity to near-halogen values and producing the characteristic yellow color.
Atomic Mass196.967 uGold is monoisotopic — ¹⁹⁷Au (100% natural abundance) is the only naturally occurring isotope, simplifying mass spectrometric analysis and making Au an ideal internal standard for ICP-MS. All other Au isotopes are radioactive.
Density (20 °C)19.32 g/cm³Among the densest elements — comparable to tungsten (19.25 g/cm³) and platinum (21.45 g/cm³). The high density is exploited historically in panning/gravity separation of placer gold and currently in density-based authentication of gold bullion against tungsten-filled counterfeits.
Melting Point1,064.18 °C (1,337.33 K)A fixed point on the ITS-90 international temperature scale (1,064.18 °C), used to calibrate high-temperature thermocouples and radiation thermometers. The relatively low melting point for a dense metal enables gold wire bonding and soldering processes in electronics manufacturing.
Boiling Point2,856 °CHigh enough to enable Au thermal evaporation for thin-film deposition (resistive boats or e-beam sources at ~1,400 °C in vacuum) and Au sputtering targets for PVD. Au evaporation is the standard method for preparing conductive coatings on biological SEM specimens.
Thermal Conductivity318 W/m·KThird highest thermal conductivity of any pure metal after Ag (429 W/m·K) and Cu (401 W/m·K). Exploited in Au-coated thermal management components in spacecraft, high-power laser optics, and Au-bonded heat spreaders in high-reliability electronics where oxidation of Cu or Ag is unacceptable.
Electrical Resistivity22.14 nΩ·m (20 °C)Fourth lowest resistivity of any pure metal after Ag (15.9), Cu (16.8), and Al (26.5 nΩ·m). Au's resistivity stability over time (no oxide film formation) makes it preferred over Cu/Ag for low-contact-resistance connectors and bond pads in high-reliability applications.
Crystal StructureFCC, a = 4.078 Å (room temperature)FCC structure gives Au 12 slip systems and is responsible for its exceptional ductility and malleability. The FCC (111) surface is the flattest and most thermodynamically stable Au surface — used as the standard substrate for thiol SAM formation and STM atomic-resolution imaging.

Mechanical Properties

PropertyValueNotes
Tensile Strength120–190 MPaLow strength in pure form — Au is the softest precious metal. Au bond wire (typically 25 µm diameter, 99.99%) requires careful mechanical characterization (loop height control, wire pull strength) to ensure reliable interconnect integrity in semiconductor packages.
Yield Strength30–100 MPaVery low yield strength — pure Au deforms easily under modest loads. Alloying (Au-Cu, Au-Ag, Au-Pt) dramatically increases strength for jewelry and industrial applications while maintaining corrosion resistance; karat gold alloys (18K = 75% Au) balance strength and color.
Young's Modulus78 GPaRelatively low modulus for a dense FCC metal — lower than Cu (130 GPa) and Ag (83 GPa). The low modulus contributes to Au's extreme malleability and is relevant to the mechanical behavior of Au thin films and MEMS structures under thermal cycling.
Hardness25–35 HBAmong the softest pure metals; work hardens rapidly. Au electroplated contacts are often hardened by co-depositing with small amounts of Co, Ni, or Fe (hard gold, 130–200 HV) to improve wear resistance in connector applications.
Elongation at Break45–55%Exceptional ductility — the highest of any metal, enabling Au to be beaten to ~0.1 µm thick leaf and drawn to wire of extraordinary fineness. Gold leaf (23–24 karat, ~0.1–0.3 µm) is used in architecture, conservation, and art gilding.
Poisson's Ratio0.44Among the highest Poisson's ratios of any FCC metal, approaching the theoretical incompressible limit of 0.5. Relevant to stress modeling of Au thin films on substrates with mismatched thermal expansion coefficients in microelectronics packaging.

Chemical Properties

PropertyValue / BehaviorNotes
Oxidation States+1 (aurous: AuCN, Au₂S, Au₂O); +3 (auric: AuCl₃, HAuCl₄, Au(OH)₃)Au³⁺ in tetrachloroaurate (AuCl₄⁻, from aqua regia dissolution) is the primary precursor for AuNP synthesis (Turkevich citrate reduction, Brust-Schiffrin two-phase synthesis). Au⁺ in KAu(CN)₂ is the standard electroplating bath species for electronics gold plating.
Corrosion ResistanceExceptional; inert to O₂, H₂O, most acids and alkalis; dissolves in aqua regia and in CN⁻/O₂Gold's thermodynamic nobility (standard reduction potential E° = +1.50 V for Au³⁺/Au, +1.83 V for Au⁺/Au) underpins its corrosion immunity. Cyanide leaching (Au + 2CN⁻ + ½O₂ + H₂O → Au(CN)₂⁻ + OH⁻) extracts ~75% of mined gold; aqua regia dissolution is used for gold assaying and recycling from electronic scrap.
Surface OxideAu₂O₃ forms above ~160 °C under oxidizing conditions; unstable — decomposes above ~300 °CThe instability of Au oxides is why Au surfaces remain clean and conductive indefinitely at ambient conditions — unlike Cu, Ag, or even Pt. This oxide-free surface is essential for reliable low-resistance electrical contacts, Au-thiol SAM formation, and Au-catalysis applications where a clean metal surface is required.
IdentifierValue
SymbolAu
Atomic Number79
CAS Number7440-57-5
UN NumberN/A
EINECS Number231-165-9
IsotopeTypeNotes
¹⁹⁷Au Stable 100% natural abundance; I = 3/2, NMR-active. Gold is monoisotopic — ¹⁹⁷Au is the only naturally occurring isotope, giving Au uniquely simple mass spectra. ¹⁹⁷Au NMR (chemical shift range ~400 ppm) characterizes Au coordination compounds and Au cluster complexes in solution, though broad quadrupolar linewidths limit routine use. ¹⁹⁷Au(n,γ)¹⁹⁸Au (σ = 98.65 barn, one of the highest of any stable nuclide) makes Au an exceptionally sensitive neutron activation analysis (NAA) target and a key flux monitor in neutron irradiation experiments.
¹⁹⁵Au Radioactive t½ = 186.1 days; EC decay to ¹⁹⁵Pt; emits X-rays and a 98.9 keV gamma. Produced by proton bombardment of Pt targets at cyclotrons. ¹⁹⁵Au's long half-life and low-energy gamma make it suitable for SPECT imaging of Au-based drug biodistribution and for Mössbauer spectroscopy studies of Au chemical bonding (¹⁹⁵Au Mössbauer is a sensitive probe of Au oxidation state and coordination geometry).
¹⁹⁸Au Radioactive t½ = 2.694 days; β⁻ (Emax = 0.961 MeV) + γ (411.8 keV, 95.6%). Produced by ¹⁹⁷Au(n,γ)¹⁹⁸Au in reactors (σ = 98.65 barn). Used clinically for radiation synovectomy (injection into inflamed joints), hepatocellular carcinoma treatment, and in colloidal ¹⁹⁸AuNP form for prostate cancer brachytherapy (sub-mm particles implanted directly into tumor). The 411.8 keV gamma enables external dosimetry and SPECT imaging of ¹⁹⁸Au distribution during treatment.

Scientific & Research Applications

Use CaseForm Typically UsedDescription
Gold Nanoparticle Synthesis & BiosensingHAuCl₄ solution (from Au metal dissolution); Au seed nanoparticles (5–20 nm)Citrate-capped AuNPs (Turkevich method) and thiol-stabilized AuNPs (Brust-Schiffrin) are functionalized with antibodies, DNA aptamers, or peptides for lateral flow immunoassays, SPR biosensors, and SERS substrates. Tunable SPR from 520 nm (spheres) to >900 nm (nanorods, nanostars) covers the biological tissue transparency window for in vivo imaging and photothermal therapy.
Surface Science & STM/AFM SubstratesAu(111) single crystal substrates; Au films on mica (template-stripped, atomically flat)Au(111) is the standard substrate for STM atomic-resolution imaging, thiol SAM characterization by XPS/NEXAFS, and electrochemical studies of molecular adsorption. Template-stripped Au on mica provides atomically flat surfaces over cm² areas for nanoparticle assembly, single-molecule SERS, and plasmonics device fabrication.
Nanocatalysis ResearchAu/TiO₂, Au/Fe₂O₃, Au/CeO₂ catalysts (2–5 nm Au particles, deposited by deposition-precipitation)Supported AuNP catalysts are active for CO oxidation at –70 °C to room temperature, selective oxidation of alcohols/aldehydes, and preferential CO oxidation (PROX) in H₂ for fuel cell applications. Research focuses on the role of the Au-support interface, particle size dependence of activity, and sintering resistance under reaction conditions.
Thin-Film Deposition & SputteringAu sputtering targets (99.99–99.999%), Au evaporation pellets/wireAu thin films (5–200 nm) deposited by thermal evaporation or DC magnetron sputtering are used for SEM specimen coating, electrical contacts on MEMS devices, Au bond pad definition in wafer-level packaging, and as seed layers for Au electroplating in microelectronics. Au's chemical inertness ensures film stability without oxidation protection.
Plasmonics & Optical ResearchAu nanorods, nanotriangles, nanostars (colloidal); Au gratings and nanodisk arrays (e-beam lithography)Au nanostructures support localized surface plasmon resonances (LSPRs) that concentrate electromagnetic fields in sub-nm "hot spots" — used for SERS detection of single molecules, tip-enhanced Raman spectroscopy (TERS), nonlinear optics, and optical tweezers. Au nanoantennas fabricated by e-beam lithography or focused ion beam milling are model plasmonic structures for near-field optical microscopy.

Industrial & Commercial Applications

SectorForm / Grade UsedDescription
Electronics & MicroelectronicsAu bond wire (25 µm, 99.99%+); Au electroplate (KAu(CN)₂ bath, 99.99%); Au-Sn solder (80Au-20Sn eutectic)Au bond wire connects die to package leads in ~80 billion semiconductor packages/year; Au electroplating protects connector contacts from oxidation and tarnish for decades of reliable service. Au-20Sn eutectic solder (mp 280 °C, flux-free, hermetic) seals lids onto ceramic packages in high-reliability RF, microwave, and aerospace applications where conventional Sn-Pb solders are prohibited.
Aerospace & Thermal ManagementAu foil/film (99.99%), Au-coated polyimide film (Kapton)Gold-coated multi-layer insulation (MLI) blankets are used on spacecraft to control radiative heat transfer — Au's low emissivity (~0.02) reflects infrared radiation and minimizes heat gain or loss in the vacuum of space. The James Webb Space Telescope's primary mirror segments are Au-coated beryllium, optimized for near-infrared reflectivity (>99% from 600 nm to 28 µm).
Medical Devices & DiagnosticsAu nanoparticles (colloidal, 20–40 nm); Au electrodes (99.99%); ¹⁹⁸Au for therapyAu nanoparticles are the active colorimetric label in lateral flow immunoassays (pregnancy tests, COVID-19 rapid tests, influenza tests) — the familiar red line results from AuNP aggregation-induced color change. Au electrodes are used in implantable neural recording arrays, cochlear implants, and retinal prostheses due to biocompatibility and electrochemical stability.
Jewelry & InvestmentAu alloys (18K = 75% Au, 14K = 58.3% Au); fine gold (99.99%, 99.999%) bullionJewelry accounts for ~50% of annual gold demand (~2,000 tonnes/year); alloying with Cu (rose gold), Ag (white gold precursor), Pd, and Ni controls color, hardness, and melting point while maintaining corrosion resistance. Investment gold (bars, coins) requires 99.5%+ purity (London Bullion Market Association "Good Delivery" standard: 99.5%).
PurityDescription
99.9% (3N)High-purity gold suitable for industrial-grade electronics, basic research, and standard coating applications where minor impurities are acceptable.
99.95% (3N5)Enhanced-purity gold ideal for demanding electronic and optical applications, offering improved consistency and performance in microfabrication processes.
99.99% (4N)Ultra-pure gold commonly used in precision electronics, high-end optical coatings, and sputtering targets where low impurity content is critical.
99.999% (5N)Research-grade gold used in advanced semiconductor processes, high-vacuum systems, and nanotechnology where maximum purity is essential for reproducibility and stability.
Synonym / Alternative NameContext
Gold metalCommercial designation for elemental Au in wire, foil, shot, powder, or target form; used in ASTM standards, London Bullion Market Association (LBMA) specifications, and trade documentation for electronics, jewelry, and investment gold supply chains.
Elemental GoldScientific designation distinguishing the pure element from HAuCl₄, KAu(CN)₂, and other Au compounds; used in nanomaterial synthesis literature to specify bulk Au as the precursor or substrate material.
Element 79Periodic table designation; used in XRF analytical software, ICP-MS databases, and nuclear data libraries (ENDF/B) where atomic number is the primary element identifier.
AurumLatin name for gold — the source of the chemical symbol Au; used in historical alchemical and early chemical literature; appears as the INN root in pharmaceutical gold compound nomenclature (auranofin, sodium aurothiomalate) and in the term "auric/aurous" for Au³⁺/Au⁺ oxidation state designation.
OrFrench language name for gold; used in French scientific literature, EU regulatory and customs documentation, and heraldic notation where "or" (gold) and "argent" (silver) are the standard metallic tinctures.
OroSpanish and Italian language name for gold; used in scientific literature and industrial/trade documentation in Spanish- and Italian-speaking markets; Spain, Mexico, and Italy are significant gold jewelry manufacturing and trading centers.