Selenium

Rubidium
See also: Selenides

Selenium (Se) is a nonmetal element with semiconductor properties and photoconductive behavior. It appears in several allotropic forms, including a metallic gray form and red amorphous powder. With a melting point of 221 °C and boiling point of 685 °C, it is moderately stable and has limited metallic conductivity that increases with light exposure. Selenium is chemically similar to sulfur and tellurium, forming compounds such as selenides and selenates.

Goodfellow offers selenium in purities ranging from 99.95% to 99.999% for a wide range of scientific and industrial applications, providing this versatile metalloid in various forms to meet diverse research and manufacturing needs. Selenium is known for its unique photoconductive properties and its ability to convert light directly into electricity, making it invaluable in several key industries. In the electronics sector, selenium is widely used in the production of photovoltaic cells and photodetectors, where its sensitivity to light enables efficient energy conversion and sensing capabilities. The glass industry utilizes selenium as a decolorizing agent and to produce red glass, taking advantage of its ability to impart specific optical properties. In the field of xerography, selenium's photoconductive nature makes it essential for manufacturing photoreceptor drums in laser printers and photocopiers. Emerging technologies benefiting from selenium include advanced solar panel designs, where selenium compounds are being explored to enhance the efficiency of thin-film solar cells. Additionally, selenium's role in quantum dot production is driving innovations in next-generation display technologies and biomedical imaging. Goodfellow's provision of high-quality selenium supports ongoing research in materials science, particularly in the areas of optoelectronics and renewable energy solutions.



General Properties

PropertyValue
Atomic Number34
Density4.81 g/cm³ (gray form)
Melting Point221 °C
Boiling Point685 °C
Thermal Conductivity0.52 W/m·K
Electrical Resistivity10⁶–10⁹ Ω·cm (amorphous)
Crystal StructureHexagonal (trigonal, gray form)

Mechanical Properties

PropertyValue
Tensile StrengthBrittle (not well defined)
Young’s Modulus10 GPa (approx.)
HardnessMohs 2
Poisson’s Ratio0.33

Chemical Properties

PropertyValue
Corrosion ResistanceStable in dry air, oxidizes in moist conditions
ReactivityCombines with metals to form selenides
Oxidation States-2, +4, +6
Surface OxideSelenium dioxide (SeO₂)
IdentifierValue
SymbolSe
Atomic Number34
CAS Number7782-49-2
UN NumberUN3283 (solid); UN3440 (liquid)
EINECS Number231-957-4
IsotopeTypeNotes
Se-74StableMinor natural isotope (~0.86%)
Se-76StableStable non-radioactive isotope (~9.23%)
Se-77StableUsed in NMR studies (~7.6%)
Se-78StableSecond most abundant (~23.7%)
Se-80StableMost abundant (~49.8%)
Se-82StableUsed in double beta decay studies (~8.82%)

Scientific Applications

Use CaseDescription
PhotovoltaicsUsed in thin-film solar cells (e.g., CIGS)
OptoelectronicsPhotoconductive layers in X-ray and light sensors
Biomedical ResearchEssential trace element in enzyme systems
Semiconductor ResearchUsed in selenide compounds (e.g., ZnSe, CdSe)
Glass AdditivesRemoves color and improves UV stability in glass

Industrial Applications

Use CaseDescription
Steel AlloyingImproves machinability and corrosion resistance
Glass ManufacturingUsed as a decolorizer and pigment
PigmentsForms red and orange pigments in plastics and ceramics
ElectronicsRectifiers and photoresistors
Chemical CatalysisSelenium compounds used as oxidation catalysts
GradeDescription
99.95% (3N5)High-purity selenium used in rectifiers, photocells, and pigment applications where minor impurities are tolerable
99.999% (5N)Ultra-pure selenium for thin-film photovoltaics, semiconductor research, and X-ray imaging sensors requiring minimal contamination
Synonym
Selenium metal
Se
Sélénium (French)
Selenio (Spanish)