Barium

Barium — Material Page
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Barium (Ba, atomic number 56) is a soft, silvery-white alkaline earth metal in Group 2 of the periodic table, immediately below calcium and strontium, and the heaviest of the common alkaline earth metals. With a density of 3.62 g/cm³ and a melting point of 727 °C, barium is softer than most structural metals (Mohs 1.25) and highly reactive — it oxidises rapidly in air, reacts vigorously with water to release hydrogen, and ignites spontaneously when finely divided. For this reason, it is stored under inert oil or anhydrous mineral spirits and handled under inert atmosphere. Its body-centerd cubic (BCC) crystal structure is typical of Group 2 metals and gives barium high symmetry but low mechanical strength. Barium's most distinctive property is its exceptional X-ray opacity, arising from its large atomic number (Z = 56) and high electron density.

The dominant industrial use of barium is as barium sulfate (BaSO₄, barite), consumed in vast quantities as a weighting agent in oil and gas drilling fluids. Barite's high density (4.48 g/cm³), chemical inertness, and non-toxicity make it the preferred additive for increasing drilling mud density to control wellbore pressure during hydrocarbon extraction — global consumption exceeds 8 million tonnes per year. In medicine, barium sulfate suspension is the standard oral contrast agent for gastrointestinal fluoroscopy and CT imaging, exploiting its extreme X-ray opacity (µ/ρ ~10 cm²/g at diagnostic X-ray energies) and insolubility in body fluids. The compound barium titanate (BaTiO₃) is a landmark ferroelectric ceramic, and the basis of virtually all multilayer ceramic capacitors (MLCCs), piezoelectric transducers, and electro-optic devices.

In advanced materials and quantum technology, barium has become unexpectedly prominent. Yttrium barium copper oxide (YBCO, YBa₂Cu₃O₇₋ₓ) was the first material to exhibit high-temperature superconductivity above liquid nitrogen temperature (Tc ~93 K), revolutionising superconductor research from 1987 onward. Barium isotopes — particularly ¹³⁷Ba⁺ and ¹³³Ba⁺ — are leading candidates for trapped-ion quantum computing platforms, with long coherence times and favorable optical transitions accessible by commercially available laser systems. Barium ferrite (BaFe₁₂O₁₉) is a hard magnetic material used in permanent magnets, recording media, and microwave absorbers. Barium oxide (BaO) and barium compounds serve as getter materials in vacuum tubes and OLED encapsulation to scavenge oxygen and water vapour.

Goodfellow offers pure barium (Ba) products designed for use in both industrial processes and scientific research. One of its most prominent uses is in the production of barium sulfate (BaSO₄), which serves as a contrast agent in medical imaging techniques such as X-rays and CT scans. This compound's radiopacity makes it ideal for enhancing image clarity during diagnostic procedures. In the oil and gas industry, barium compounds are used as weighting agents in drilling fluids to stabilize wellbores during extraction processes. Additionally, barium finds applications in electronics manufacturing, particularly in vacuum tubes and cathode ray tubes (CRTs), where it acts as a getter material to remove residual gases. Advanced technologies benefiting from barium include energy storage systems like batteries and supercapacitors, where it contributes to improved performance and efficiency. Goodfellow's barium products enable researchers to explore new frontiers in materials science while supporting critical industrial applications that rely on its unique properties.

General Properties

PropertyValueNotes
Atomic Number56Group 2 (alkaline earth metal), Period 6; heaviest common alkaline earth metal
Atomic Mass137.327 uSeven stable isotopes; ¹³⁸Ba most abundant (71.7%)
Density (20 °C)3.62 g/cm³Denser than calcium (1.54) and strontium (2.64) but lighter than most transition metals; floats on many organic solvents
Melting Point727 °C (1000 K)Relatively low for a metal; accessible in conventional furnace equipment; reactive melt requires inert atmosphere
Boiling Point1845 °C (2118 K)Wide liquid range; barium vapour used in vacuum tube getter flash evaporation
Thermal Conductivity18.4 W/m·KLow thermal conductivity relative to most metals; not used in thermal management applications
Specific Heat Capacity204 J/kg·KLow heat capacity; relevant for thermal modeling in YBCO processing and ceramic sintering
Electrical Resistivity332 nΩ·m (20 °C)~13× higher than copper; not used as an electrical conductor; relevant for understanding BaTiO₃ and YBCO electronic behavior
Crystal StructureBody-Centred Cubic (BCC)BCC structure at room temperature; transforms to other phases at high temperature; lattice parameter a = 5.023 Å
Vapour Pressure~1 Pa at 638 °CSignificant vapour pressure below melting point; enables vacuum evaporation for getter applications

Mechanical Properties

PropertyValueNotes
HardnessMohs 1.25Very soft — can be cut with a knife; similar in feel to lead; must be handled with care to avoid deformation
Elastic (Young's) Modulus13 GPaAmong the lowest of any metal; not used in structural applications; relevant for YBCO film stress modeling
Poisson's Ratio~0.30Estimated from elastic constants; typical for BCC metals

Thermal & Environmental Properties

PropertyValue / BehaviourNotes
Reactivity with AirRapid oxidation; ignites if finely dividedForms BaO and Ba₃N₂ on surface; bulk metal tarnishes within minutes in ambient air; powder is pyrophoric — classified as a flammable solid (UN1400, Class 4.3)
Reactivity with WaterVigorous — releases H₂Ba + 2H₂O → Ba(OH)₂ + H₂↑; more reactive than calcium; reaction is exothermic and potentially hazardous with bulk quantities
ToxicologySoluble Ba compounds are toxicSoluble barium salts (BaCl₂, Ba(NO₃)₂) are acutely toxic — TLV-TWA 0.5 mg/m³ (ACGIH); BaSO₄ is essentially inert and non-toxic; elemental Ba causes chemical burns on contact with moisture
StorageUnder mineral oil or inert atmosphereMust not be stored in contact with air or water; supplied in sealed ampoules under argon or submerged in anhydrous mineral oil

Chemical Properties

PropertyValue / BehaviourNotes
Oxidation State+2 (exclusively)Ba²⁺ is the only stable oxidation state; ionic radius 1.35 Å — one of the largest common cations, which governs its coordination chemistry and crystal structures
Key Compound: BaSO₄Insoluble in water (Ksp ~1×10⁻¹⁰)Extreme insolubility and high density (4.48 g/cm³) make it safe for medical use and ideal as drilling mud additive; melting point 1580 °C; chemically inert to most acids
Key Compound: BaTiO₃Perovskite ferroelectric (Tc ~120 °C)Curie temperature 120 °C; spontaneous polarisation ~26 µC/cm²; dielectric constant up to ~10,000 near Tc; the archetypal ferroelectric material underpinning MLCC technology
Key Compound: YBCOTc ~93 K (liquid N₂ superconductor)YBa₂Cu₃O₇₋ₓ; first material to superconduct above 77 K; used in superconducting wire, fault current limiters, MRI magnets, and quantum sensors
IdentifierValue
SymbolBa
Atomic Number56
CAS Number7440-39-3
UN NumberUN1400 (solid); UN1884 (oxide)
EINECS Number231-149-1
IsotopeTypeNotes
¹³⁸Ba Stable 71.7% natural abundance; most abundant stable Ba isotope; used as reference in Ba isotope ratio measurements
¹³⁷Ba Stable 11.2% natural abundance; ¹³⁷Ba⁺ is a leading candidate qubit for trapped-ion quantum computing — long-lived optical transition at 455 nm amenable to diode laser control
¹³⁶Ba Stable 7.8% natural abundance; used in isotope dilution mass spectrometry (IDMS) for precise Ba quantification in geological and environmental samples
¹³⁵Ba Stable 6.6% natural abundance; I = 3/2, NMR-active (¹³⁵Ba NMR used to probe BaTiO₃ and barium perovskite local structure)
¹³⁴Ba Stable 2.4% natural abundance; used as a spike isotope in multi-collector ICP-MS for Ba isotope geochemistry
¹³³Ba Radioactive t½ = 10.5 yr (EC); strong gamma emitter (356 keV); used as a gamma calibration source and in nuclear medicine research; ¹³³Ba⁺ is explored as an alternative trapped-ion qubit
¹³⁷mBa Radioactive t½ = 2.55 min (IT); the daughter of ¹³⁷Cs decay; the standard ¹³⁷Cs/¹³⁷mBa generator system is used for gamma calibration and nuclear physics demonstrations

Scientific & Research Applications

Use CaseForm Typically UsedDescription
Trapped-Ion Quantum ComputingIsotopically enriched ¹³⁷Ba, ¹³³Ba¹³⁷Ba⁺ ions have optical clock transitions at 455 nm and 614 nm accessible with commercially available diode lasers, long coherence times, and a nuclear spin (I = 3/2) enabling hyperfine qubit encoding. University of Maryland and IonQ have demonstrated entangled barium qubit registers. ¹³³Ba⁺ (t½ = 10.5 yr) is also investigated as a radioactive qubit species for fundamental symmetry tests.
High-Temperature Superconductor ResearchBa metal, BaCO₃, BaO powdersBarium is an indispensable constituent of YBCO (YBa₂Cu₃O₇₋ₓ, Tc ~93 K) — the workhorse high-Tc superconductor for coated conductor tape, fault current limiters, and superconducting magnets. Ba is also present in Bi-Sr-Ca-Cu-O (BSCCO), thallium-based, and mercury-based cuprate superconductors, and in the recently discovered nickelate superconductors.
Ferroelectric & Piezoelectric ResearchBaTiO₃ single crystals, thin filmsBaTiO₃ is the archetypal displacive ferroelectric — the model system for understanding spontaneous polarisation, domain switching, and electromechanical coupling. Single-crystal PMN-PT (Pb(Mg₁/₃Nb₂/₃)O₃–PbTiO₃) and Ba-substituted variants achieve piezoelectric coefficients d₃₃ >2,000 pC/N. BaTiO₃ thin films are studied for memristor and neuromorphic computing applications.
Vacuum Tube Getter ResearchBa metal, BaAl₄ alloy ringsBarium is the dominant flash getter in vacuum tubes and cathode ray tubes: a BaAl₄ or BaNi alloy ring is inductively heated in vacuum to evaporate a Ba film onto the tube envelope interior, where it chemisorbs residual O₂, N₂, CO, CO₂, and H₂O at rates of ~1 monolayer/s. The mirror-like Ba spot is the visible indicator of tube vacuum integrity.
Nonlinear OpticsBBO (β-BaB₂O₄) crystalsBeta-barium borate (BBO, β-BaB₂O₄) is among the most widely used nonlinear optical crystals for second-harmonic generation (SHG), optical parametric oscillation (OPO), and sum/difference frequency generation. Its wide transparency (190–3500 nm), high damage threshold (~10 GW/cm²), and large nonlinear coefficient (d₂₂ = 2.2 pm/V) make it ubiquitous in ultrafast laser systems.
X-Ray Absorption SpectroscopyBa foil, BaSO₄ standardsThe Ba L-edges (L₁ = 5247 eV, L₂ = 4965 eV, L₃ = 4966 eV) are accessible with synchrotron radiation and used to characterise Ba oxidation state and local coordination in perovskites, YBCO, and geological materials by XANES and EXAFS.

Industrial & Commercial Applications

SectorForm / Compound UsedDescription
Oil & Gas Drilling FluidsBaSO₄ (barite), API GradeBarite (BaSO₄, SG 4.2–4.5) is the primary weighting agent in water-based and oil-based drilling muds, used to increase fluid density to 9–19 lb/gal to control formation pressure and prevent blowouts. Global consumption exceeds 8 million tonnes/year — the largest single use of barium compounds. API 13A specifies particle size and chemical purity requirements.
Multilayer Ceramic Capacitors (MLCCs)BaTiO₃ powder and thin filmsBaTiO₃-based dielectrics are the active material in virtually all MLCCs — over 4 trillion units produced annually for smartphones, automotive electronics, and IoT devices. Class II X5R/X7R dielectrics achieve capacitances of 1–100 µF in packages as small as 0201 (0.6×0.3 mm) by exploiting the very high dielectric constant of doped BaTiO₃ near its Curie point.
Medical Imaging ContrastBaSO₄ suspension (Baritop, E-Z-HD)Barium sulfate suspension (typically 100–250% w/v) is the standard oral and rectal contrast agent for fluoroscopic and CT examination of the GI tract. Its extreme X-ray opacity and complete GI inertness (Ksp ~10⁻¹⁰, non-absorbed) make it uniquely suited for this purpose. Contraindicated in suspected GI perforation, where water-soluble iodinated contrast is substituted.
Permanent Magnets & Microwave AbsorbersBaFe₁₂O₁₉ (barium ferrite)Barium hexaferrite is a hard magnetic material (Hc ~300 kA/m, (BH)max ~30 kJ/m³) used in low-cost permanent magnets for speakers, DC motors, and magnetic door catches. Its high electrical resistivity and planar magnetic anisotropy make it effective for microwave and millimetre-wave absorbers in the 1–100 GHz range — increasingly important for EMC shielding in 5G infrastructure.
OLED & Display EncapsulationBa metal thin films, BaOThin films of evaporated barium (typically 1–5 nm) serve as low work-function electron injection layers in OLED devices, significantly improving electron injection efficiency and device lifetime. Barium getter films are also used inside hermetic display enclosures to scavenge water vapour — the primary degradation agent for organic emissive layers — extending display operational lifetime.
Pyrotechnics & Signal FlaresBa(NO₃)₂, BaClO₄, BaCl₂Barium compounds are the primary source of green color in pyrotechnics, producing characteristic emission lines from BaCl and BaOH radicals at 513–524 nm. Barium nitrate is used as an oxidiser and green colorant in military signal flares, tracer ammunition, and commercial fireworks.
GradePurityMain Use
Barium (Standard Purity)99%Suitable for general scientific research, ceramic synthesis, and alloying studies — including YBCO and barium titanate precursor work, vacuum getter development, and exploratory inorganic chemistry where trace-metal content is not critical to the application
Synonym / Alternative NameContext
BaChemical symbol; from Greek barys (βαρύς), meaning heavy
BaryumFrench language name; also used in older English literature
BarioSpanish and Italian language equivalent
Elemental bariumGeneral commercial and regulatory term for the pure metal
Barium metalStandard commercial designation to distinguish from barium compounds (BaSO₄, BaTiO₃, etc.)