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ETFE Film

Available Configurations

Properties common to all products in this list

Commodity: Polymers Material: Ethylene tetrafluoroethylene (ETFE) Form: Foil/Film/Sheet Composition: ETFE Grade: Copolymer CAS Number: 25038-71-5
Thickness Size
0.025 mm to 0.25 mm 10 x 10 mm to 500 x 500 mm

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ETFE Film (ethylene tetrafluoroethylene) is a partially fluorinated copolymer film combining the UV and weathering resistance of fluoropolymers with better mechanical toughness than fully fluorinated grades, delivering tensile strength of 40-50 MPa, elongation of 100-300%, upper service temperature of 150-200°C, volume resistivity of 10¹⁵ Ωcm, and a V0 flammability rating with limiting oxygen index of 31%. A defining characteristic is its outstanding UV and solar transmission: ETFE transmits approximately 90% of solar UV-B radiation, making it unique among common plastic films in supporting UV-dependent biological and photochemical processes beneath the film surface. In industry, ETFE film is used for architectural roofing cushions in large-span structures such as stadia and atria, greenhouse covering where UV transmission supports natural pathogen suppression and improved crop quality, photovoltaic module front sheets where its electrical output and reliability match glass performance at substantially lower weight, wire and cable insulation in aerospace wiring, and high-temperature release films in composite manufacturing. In research, it is used for UV transmission and photostability studies, agricultural controlled-environment research comparing UV-blocking and UV-transmitting coverings, and solar energy harvesting film development where its balance of transparency, chemical stability, and weathering resistance makes it a reference fluoropolymer substrate.
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Key Features

ETFE Film (ethylene tetrafluoroethylene) is a partially fluorinated copolymer film combining the UV and weathering resistance of fluoropolymers with better mechanical toughness than fully fluorinated grades:

Outstanding UV and Solar Transmission

ETFE transmits approximately 90% of solar UV-B radiation, making it unique among common plastic films in supporting UV-dependent biological and photochemical processes beneath the film surface. No other widely available plastic film achieves comparable UV-B transmission at practical thicknesses.

Better Mechanical Toughness Than Fully Fluorinated Grades

Tensile strength of 40–50 MPa and elongation of 100–300% give ETFE considerably better toughness than PTFE or FEP while retaining the fluoropolymer family’s chemical resistance and surface properties.

High-Temperature Capability

Upper service temperature of 150–200 °C supports use in composite manufacturing release films and aerospace wiring environments where standard polymer films would degrade. The V0 flammability rating and limiting oxygen index of 31% additionally qualify it for aerospace applications.

Reliable Electrical Insulation

Volume resistivity of 10¹⁵ Ω·cm provides reliable electrical insulation for wire and cable applications in aerospace wiring, where the V0 flammability rating is simultaneously required.

UV Stability and Weathering Durability

Fluoropolymer chemical inertness and outstanding UV stability provide long-term durability in outdoor and chemically aggressive environments, supporting multi-decade service in architectural and photovoltaic applications.

Industrial Applications

ETFE Film is used across architecture, agriculture, photovoltaics, aerospace wiring, and composite manufacturing wherever UV transmission, weathering durability, and fluoropolymer chemical resistance determine material selection:

✦ Architectural Roofing Cushions in Large-Span Structures
Used for pneumatic cushion roofing systems in stadia and atria, where UV and weathering durability over decades of outdoor exposure and the low weight relative to glass qualify ETFE as the standard material for large-span transparent enclosure structures.
✦ Greenhouse and Controlled-Environment Covering
Applied as greenhouse covering where UV transmission supports natural pathogen suppression and improved crop quality, distinguishing ETFE from UV-blocking plastic films that suppress these effects.
✦ Photovoltaic Module Front Sheets
Used as PV module front sheet film where electrical output and long-term reliability match glass performance at substantially lower weight, supporting lightweight module designs.
✦ Aerospace Wire and Cable Insulation
Applied as wire and cable insulation in aerospace wiring where the V0 flammability rating, elevated service temperature, and volume resistivity meet aerospace electrical insulation specifications.
✦ High-Temperature Release Films in Composite Manufacturing
Used as release films in composite manufacturing where the upper service temperature and non-stick fluoropolymer surface support clean demolding at elevated cure temperatures.
✦ UV Transmission, Photostability and Solar Energy Research
Used for UV transmission and photostability studies, agricultural controlled-environment research comparing UV-blocking and UV-transmitting coverings, and solar energy harvesting film development where its balance of transparency, chemical stability, and weathering resistance makes it a reference fluoropolymer substrate.

Material Properties

Chemical Resistance
Element Value
Acids - concentrated Good
Acids - dilute Good
Alcohols Good
Alkalis Good
Aromatic hydrocarbons Good
Greases and Oils Good
Halogenated Hydrocarbons Good
Halogens Good
Ketones Good
Electrical Properties
Element Value
Dielectric constant @1MHz 2.6
Dissipation factor @ 1MHz 0.0005
Dielectric strength( kV mm⁻¹ ) 25
Surface resistivity( Ohm/sq ) >10¹⁴
Volume resistivity( Ohmcm ) 10¹⁶
Physical Properties
Element Value
Flammability V0
Radiation resistance Fair
Refractive index 1.403
Resistance to Ultra-violet Excellent
Limiting oxygen index( % ) 30-32
Water absorption( % ) 0-0.03
Density( gcm⁻³ ) 1.7
Mechanical Properties
Element Value
Hardness - Rockwell R50
Elongation at break( % ) 250-350
Tensile modulus( GPa ) 0.8
Izod impact strength( J m⁻¹ ) 1000
Tensile strength( MPa ) 28-48
Thermal Properties
Element Value
Heat-deflection temperature - 0.45MPa( C ) 105
Heat-deflection temperature - 1.8MPa( C ) 70
Lower working temperature( C ) -100
Upper working temperature( C ) 150-160
Specific heat( J K⁻¹ kg⁻¹ ) 1900-2000
Thermal conductivity( W m⁻¹ K⁻¹ ) 0.24@23°C
Coefficient of thermal expansion( x10⁻⁶ K⁻¹ ) 90-170
each

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Available Configurations

Properties common to all products in this list

Commodity: Polymers Material: Ethylene tetrafluoroethylene (ETFE) Form: Foil Composition: ETFE Grade: Copolymer CAS Number: 25038-71-5

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Tolerances

Foil
Thickness ±20%
Linear dimension <100mm ±1mm
Linear dimension >=100mm +2 / -1%