Zinc Oxide ZnO - Material Information

ZnO
March 5, 2024
Zinc Oxide ZnO - Material Information

Zinc Oxide (ZnO) is a multifunctional inorganic compound known for its unique semiconducting, optical, and piezoelectric properties, making it one of the most versatile materials in modern science and industry. Structurally, ZnO crystallizes in a wurtzite lattice—a hexagonal structure that imparts strong anisotropy to its electronic and optical behavior (Adachi, 1999). Physically, it is a white, nearly insoluble powder with a wide direct bandgap of approximately 3.4 eV at room temperature, enabling high transparency in the visible region and strong absorption in the ultraviolet (UV) range (Chauhan et al., 2024).

Material Overview

Zinc oxide’s combination of high exciton binding energy (~60 meV) and excellent chemical stability makes it a promising semiconductor material for optoelectronic devices, sensors, and UV photodetectors. Its ability to scatter and absorb UV radiation underpins its use in sunscreens, coatings, and optical filters (Ji & Nafees, 2023).

Chemically, ZnO is an amphoteric oxide that can react with both acids and bases, forming zinc salts and zincates, respectively. It exhibits high electrochemical coupling coefficients and piezoelectricity, enabling applications in transducers, actuators, and sensors across fields from biomedicine to automotive engineering (Sharma et al., 2022).

Physical and Chemical Properties

ZnO’s optical transparency and conductivity make it an attractive alternative to indium tin oxide (ITO) in transparent conductive films for LEDs, touch screens, and solar cells. Its photoconductivity and UV sensitivity also enable its use in UV detectors and surface acoustic wave (SAW) filters (Rogers et al., 2013; Jandow et al., 2012).

From a materials science perspective, ZnO’s physical characteristics—such as high hardness, melting point (1975 °C), and thermal conductivity—allow it to function as a ceramic material and high-temperature dielectric. Additionally, its biocompatibility and antimicrobial properties have made it valuable in medical and cosmetic applications (Игрутиновић, 2023).

Applications and Advantages

Optoelectronics and energy devices. ZnO is widely used in photovoltaics, LEDs, varistors, and transparent conducting electrodes. Its high electron mobility and cost-effectiveness make it a preferred choice for next-generation solar cell architectures (Chauhan et al., 2024).

Nanotechnology and coatings. ZnO nanoparticles and thin films are applied in antimicrobial coatings, energy storage devices, and photocatalysts. In nanomedicine, they are explored for drug delivery systems and biosensors due to their surface reactivity and stability (Ji & Nafees, 2023).

Consumer and industrial applications. Owing to its UV-blocking capacity and skin compatibility, ZnO is used in sunscreens, cosmetics, rubber vulcanization, ceramics, paints, and pharmaceuticals. The U.S. FDA recognizes ZnO as safe for human use, supporting its broad adoption in consumer products (Sharma et al., 2022).

Performance Benefits

  • Wide bandgap (≈3.4 eV) and high UV absorption capacity.
  • High exciton binding energy and optical transparency.
  • Excellent piezoelectric and photoconductive properties.
  • Chemical stability, oxidation resistance, and biocompatibility.
  • Applicable in both bulk and nanostructured forms (nanorods, films, powders).

Goodfellow Availability

Goodfellow supplies Zinc Oxide (ZnO) in powder and sputtering target forms for applications in electronics, coatings, photonics, and biomedical research. ZnO’s multifunctionality and compatibility with various processing methods make it a cornerstone material for both scientific and industrial innovation.

Explore Zinc Oxide (ZnO) and other advanced functional oxides in Goodfellow’s online catalogue: Goodfellow product finder.

References

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