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Mercury ( Hg )

Material Information

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General Description:  

Mercury was known to ancient civilisations.

The chemical symbol, Hg, comes from the Latin word "hydragyrum" which means liquid silver, it being the most common liquid metal at room temperature. As a liquid, the metal is extremely mobile and dense and as a solid, it is ductile and malleable (mercury has a melting point of -39C). It is a readily accessible element as it occurs in concentrated ores, mercury (II) oxide being decomposed by heating alone at around 500C (i.e. with no reducing agent), at which temperature mercury distils out. The element and many of its compounds are extremely toxic and, as mercury has a relatively high vapour pressure at room temperature, mercury surfaces should always be kept covered to reduce vapourisation.

The use of mercury and its compounds has been reduced due to its toxicity. However, as it acts a "solvent" with most metals where it forms amalgams, it has some use in the field of dental amalgams. It is also used in mercury vapour lamps and many scientific and electrical instruments. One application with which many people will be familiar is the mercury barometer, an instrument used for measuring the pressure of the atmosphere in terms of the height of a column of mercury which exerts an equal pressure.

   

Atomic Properties

Atomic number 80
Atomic radius - Goldschmidt ( nm ) 0.155
Atomic weight ( amu ) 200.59
Crystal structure Rhombohedral
Electronic structure Xe 4f14 5d1O 6s2
Ionisation potential No. eV
1 10.44
2 18.76
3 34.2
Natural isotope distribution Mass No. %
196 0.2
198 10.1
199 16.9
200 23.1
201 13.2
202 29.7
204 6.8
Photo-electric work function ( eV ) 4.49
Thermal neutron absorption cross-section ( Barns ) 375
Valences shown 1, 2

Electrical Properties

Electrical resistivity @20C ( µOhmcm ) 95.9
Temperature coefficient @0-100C ( K-1 ) 0.001
Superconductivity critical temperature ( K ) 4.15
Thermal emf against Pt (cold 0C - hot 100C) ( mV ) 0.045

Mechanical Properties

Material condition Liquid
Bulk modulus ( GPa ) 25

Physical Properties

Boiling point ( C ) 357
Density @20C ( g cm-3 ) 13.6
Melting point ( C ) -38.87

Thermal Properties

Coefficient of thermal expansion @0-100C ( x10-6 K-1 ) 61
Latent heat of evaporation ( J g-1 ) 300
Latent heat of fusion ( J g-1 ) 11.5
Specific heat @25C ( J K-1 kg-1 ) 138
Thermal conductivity @0-100C ( W m-1 K-1 ) 8.65

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